I looked at the last 10 years worth of games.
National telecasts - NBC, ABC, Fox, or ESPN are all that matter.
Syracuse has played in 27 such games, NC State 31.
Here is the tale of the tape:
Syracuse -
8 - Clemson
5 - Notre Dame and Florida State
1 - Penn State, MD, NC State, LSU, Louisville, Pitt, BC, Miami, UVa
NC State -
8 - Clemson
5 - UNC
4 - Florida State
2 - Notre Dame, VT, Louisville, and Wake Forest
1 - West Virginia, Miami, South Carolina, Syracuse, ECU, and BC
NC State lost two home games, one with West Virginia and one with Mississippi State over this span.
I don't think it matters.
NC State football schedules tend to be local/regional affairs. Games against big TV draws outside Clemson and FSU are rare. There is nothing special about Raleigh that can not be found with a traveling schools visit to Duke or UNC.
Syracuse on the other hand is upstate NY, and by extension NYC.
NC State COULD draw more television eyes but actively avoids it by who it schedules, the two weeks in October it refuses to play at home due to the North Carolina State Fair, and the strong demand not to kick off before 7PM in the month of September.
I don't think Syracuse is owed any football umbrage from the ACC. Now basketball - that's another matter but then again it will need to be someone other than NC State casting the basketball aspersions.